Publications


Delley, M. F.*; Nichols, E. M.; Mayer, J. M.
"Electrolyte Cation Effects on Interfacial Acidity and Electric Fields" 
J. Phys. Chem. C 2022, 126, 8477.

TOC cation sam

Delley, M. F.†,*; Nichols, E. M.†,*; Mayer, J. M.*
"Interfacial Acid/Base Equilibria and Electric Fields Concurrently Probed by In-Situ Surface-Enhanced Infrared Spectroscopy" 
JACS 2021,143, 10778.

SAM TOC

Castillo-Lora, J.; Delley, M. F.; Laga, S. M.; Mayer, J. M. ( equal contributions)
"Two-electron-two-proton reduction from colloidal ZnO and TiO2 nanoparticles to molecular substrates"
J. Phys. Chem. Lett. 202011, 7687.

MultiPCET TOC

 

Delley, M. F.*; Wu, Z.; Mundy, M. E.; Ung, D.; Cossairt, B. M.; Wang, H.; Mayer, J. M.*
"Hydrogen on Cobalt Phosphide" 
JACS 2019141, 15390.

""

 

Saouma, C. T.; Richard, S.; Smolders, S.; Delley, M. F.; Ameloot, R.; Vermoortele, F.; De Vos, D. E.; Mayer, J. M.
"Bulk-to-Surface Proton-Coupled Electron Transfer Reactivity of the Metal-Organic Framework MIL-125"
JACS 2018140, 16184.

""

 

Valdez, C. N.Delley, M. F.; Mayer, J. M. ( equal contributions)
"Cation Effects on the Reduction of Colloidal ZnO Nanocrystals"
JACS 2018, 140, 8924.

ZnO Cations TOC

Copéret, C.; Allouche, F.; Chan, K. W.; Conley, M. P.; Delley, M. F.; Fedorov, A.; Moroz, I. B.; Mougel, V.; Pucino, M.; Searles, K.; Yamamoto, K.; Zhizhko, P. A.
"Bridging the Gap between Industrial and Well-Defined Supported Catalysts"
Angew. Chem. Int. Ed. 2018, 57, 6398.

Bridging the gap review TOC

Delley, M. F.; Lapadula, G.; Núñez-Zarur, F.; Comas-Vives, A.; Kalendra, V.; Jeschke, G.; Baabe, D.; Walter, M. D.; Rossini, A. J.; Lesage, A.; Emsley, L.; Maury, O.; Copéret, C.
"Local Structures and Heterogeneity of Silica-Supported M(III) Sites Evidenced by EPR, IR, NMR, and Luminescence Spectroscopies" 
JACS 2017, 139, 8855.

Local Structures TOC

Delley, M. F. ; Praveen, C. S.; Borosy, A. P.; Núñez-Zarur, F.; Comas-Vives, A.; Copéret, C.
"Olefin Polymerization on Cr(III)/SiO 2 : Mechanistic Insights from the Differences in Reactivity between Ethene and Propene" 
J. Catal. 2017, 354, 223.

mechanistic insights TOC

Delley, M. F.; Silaghi, M.-C.; Núñez-Zarur, F.; Kovtunov, K. V.; Salnikov, O. G.; Estes, D. P.; Koptyug, I. V.; Comas-Vives, A.; Copéret, C. 
"X–H Bond Activation on Cr(III),O Sites (X = R,H): Key Steps in Dehydrogenation and Hydrogenation Processes" 
Organometallics 2017, 36, 234.

hydrogenation dehydrogenation TOC

Delley, M. F.* 
"A Molecular Approach to Well-Defined Metal Sites Supported on Oxides with Oxidation State and Nuclearity Control"
CHIMIA 2015, 69(4), 168.

Conley, M. P.Delley, M. F.; Núñez-Zarur, F.; Comas-Vives, A.; Copéret, C. ( equal contributions)
"Heterolytic Activation of C–H Bonds on Cr III –O Surface Sites is a Key Step in Catalytic Polymerization of Ethylene and Dehydrogenation of Propane" 
Inorg. Chem. 2015, 54, 5065.

heterolytic splitting forum article TOC

Delley, M. F.; Núñez-Zarur, F.; Conley, M. P.; Comas-Vives, A.; Siddiqi, G.; Norsic, S.; Monteil, V.; Safonova, O. V.; Copéret, C. 
"Proton Transfers are Key Elementary Steps in Ethylene Polymerization on Isolated Chromium(III) Silicates" 
PNAS 2014, 111, 11624.

Delley, M. F.; Conley, M. P.; Copéret, C. 
"Polymerization on CO-Reduced Phillips Catalyst Initiates through the C–H Bond Activation of Ethylene on Cr–O Sites" 
Catal. Lett.  2014, 144, 805.

Phillips polymerization TOC

Conley, M. P.; Delley, M. F.; Siddiqi, G.; Lapadula, G.; Norsic, S.; Monteil, V.; Safonova, O. V.; Copéret, C. 
"Polymerization of Ethylene by Silica-Supported Dinuclear Cr III Sites through an Initiation Step Involving C–H Bond Activation" 
Angew. Chem. Int. Ed. 2014, 53, 1872.


Patents

Delley, M. F.; Conley, M. P.; Copéret, C. 
"Chromium(III) Silicate Catalysts Suitable for PE Synthesis"
2013, EP2826795A1, WO2015007828.